Organometal-Catalyzed Asymmetric Synthesis Stereocontrolled by Organosulfur Functionality
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چکیده
منابع مشابه
Stereocontrolled Synthesis of Bicyclic Sulfamides via Pd-Catalyzed Alkene Carboamination Reactions. Control of 1,3-Asymmetric Induction by Manipulating Mechanistic Pathways
A new annulation strategy for the synthesis of trans-bicyclic sulfamides is described. The Pd-catalyzed alkene carboamination reactions of 2-allyl and cis-2,5-diallyl pyrrolidinyl sulfamides with aryl and alkenyl triflates afford the fused bicyclic compounds in good yields and with good diastereoselectivity (up to 13:1 dr). Importantly, by employing reaction conditions that favor an anti-aminop...
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ژورنال
عنوان ژورنال: YAKUGAKU ZASSHI
سال: 2000
ISSN: 0031-6903,1347-5231
DOI: 10.1248/yakushi1947.120.9_733